Robot vacuums
A robot vacuum runs on its battery while it cleans, then draws power from the dock to recharge. If you schedule its run to finish around 9pm, most of the recharging lands in the lower-rate hours. Keep the dock on a hard, clear surface and follow the manufacturer's guidance on where it sits.
Cordless stick vacuums
Most of these live on their wall charger full time. Plugging the charger into a smart plug set to run from 9pm to midnight tops the battery up in the lower-rate hours, and it means the vacuum isn't left charging indefinitely.
Laptops and tablets
Charge them in the evening while you're winding down, on a hard, flat surface rather than a bed or couch. Many laptops have battery care settings that stop charging at around 80%, which is easier on the battery over time.
Phones
The energy is tiny, so timing makes little difference to your bill. Many phones have optimised or adaptive charging that slows things down overnight. If you charge beside the bed, put the phone on the bedside table rather than on the bed or under a pillow.
E-bikes and e-scooters
These are the biggest batteries most homes have after an EV. Charge them after 9pm while you're home and awake, using the charger supplied, on a hard surface and away from exits. Unplug once the battery is full rather than leaving it charging overnight.
Updates, backups and downloads
Computers and consoles can often schedule big downloads and backups for overnight. Keep in mind that a console left in rest mode to do this uses more power than one that's switched off, so it's a trade-off rather than a free win.